刘太宏 副教授

毕业学校：陕西师范大学

电     话：187-****-5697

电子邮箱：liuth121@snnu.edu.cn

研究方向：光物理技术；荧光传感；自组装；双光子成像

讲授课程：

人个简介：

河南省周口市人。2005年毕业于陕西师范大学化学教育专业，获得学士学位，后即作为研究生支教团一员参加了为期一年的研究生支教工作。2006年至2012年师从房喻教授主要从事寡聚噻吩衍生物的单分子层组装、光物理行为及其传感应用研究，顺利取得工学博士学位并被授予陕西师范大学优秀毕业生。2012年10月加入美国中佛罗里达大学化学系Kevin D. Belfield 教授课题组进行博士后研究，主要从事双光子染料合成及其在光化学动力学治疗和细胞成像方面的研究。2014年11月至2017年10月在美国新泽西理工学院进行博士后研究，研究方向仍关注双光子材料的制备及其生物应用。2017年10月入职陕西师范大学化学化工学院工作。

研究兴趣将集中关注近红外双光子荧光染料的设计、制备和应用研究，目标实现对水体、细胞和生物组织内重要物质的灵敏荧光检测和高效生物成像。

加入SNNU后（2017年10月至今）

【在研项目】

【4】国家自然科学基金项目（双光子荧光界面探针创制及其在液/液界面膜形成机制研究中的应用，22172097），2022年1月~2025年12月，主持在研

【3】军事科学院防化研究院合作项目，2021年1月~2022年12月，主持在研

【2】陕西省科技创新团队项目（2021TD-18），2021年1月~2023年12月，参与在研

【1】NSF国际（地区）合作与交流项目（21810102005，面向创新制备和高性能化的荧光敏感薄膜基质效应研究，240万元），2019年1月~2023年12月，参与在研

代表性成果：

2022年

[22] Qingwei Jiang, Zhaolong Wang, Gang Wang, Ke Liu, Wenjun Xu, Congdi Shang, Xinyu Gou, Taihong Liu*, Yu Fang*. A Configurationally Tunable Perylene Bisimide Derivative-based Fluorescent Film Sensor for the Reliable Detection of Volatile Basic Nitrogen towards Fish Freshness Evaluation. Chinese J. Chem. 2022, 40, 201-208. (共同通讯作者)

https://doi.org/10.1002/cjoc.202100626

[21] Jiayin Zhao, Molin Qin, Jiawen You, Ke Liu, Liping Ding, Taihong Liu*, Jinglin Kong*, and Yu Fang. Rapid and Colorimetric Evaluation of G-Series Nerve Agents and Simulants Using the Squaraine-ethanolamine Adducts. Dyes. Pigments 2022, 197, 109870. (共同通讯作者)

2021年

[20] Zhaolong Wang, Yue Sun, Simin Lin, Gang Wang, Xingmao Chang, Xinyu Gou, Taihong Liu*, Shengye Jin, Gang He, Yu-Chen Wei, Pi-Tai Chou, and Yu Fang*. Orthogonal Carbazole-perylene bisimide Pentad: A Photoconversion-tunable Photosensitizer with Diversified Excitation and Excited-state Relaxation Pathways. Sci. China Chem. 2021, 64, 2193-2201. (共同通讯作者)

https://doi.org/10.1007/s11426-021-1154-0

[19] Wan Feng, Ke Liu, Jianyang Zang, Jiale Xu, Haonan Peng, Liping Ding, Taihong Liu,* and Yu Fang.  Resonance Enhanced Two-Photon Absorption and Optical Power Limiting Properties of Three-dimensional Perylene Bisimide Derivatives. J. Phys. Chem. B 2021, 125, 41, 11540-11547.

[18] Wan Feng, Ke Liu, Jianyang Zang, Gang Wang, Rong Miao, Liping Ding, Taihong Liu*, Jinglin Kong*, and Yu Fang. Flexible and Transparent Oligothiophene-o-Carborane-Containing Hybrid Films for Nonlinear Optical Limiting Based on Efficient Two-Photon Absorption. ACS Appl. Mater. Interfaces 2021, 13, 28985−28995. DOI:10.1021/acsami.1c07835. （共同通讯作者）

[17] Jianyang Zang, Wan Feng, Xingmao Chang, Ke Liu, Haonan Peng, Liping Ding, Taihong Liu*, and Yu Fang. Enhanced Two-Photon Absorption of Sandwich-Like Coordination Complexes Based on Squaraine and Metallomacrocycle Derivatives. Dyes Pigm. 2021, 193, 109487.

[16] Ke Liu, Gang Wang, Nannan Ding, Jing Zhang, Jinglin Kong, Taihong Liu*, and Yu Fang*. High-Performance Trichloroacetic Acid Sensor Based on the Intramolecular Hydrogen Bond Formation and Disruption of a Specially Designed Fluorescent o-Carborane Derivative in the Film State. ACS Appl. Mater. Interfaces 2021,13 (16), 19342-19350. Doi: 10.1021/acsami.1c03331.（共同通讯作者）

[15] Jing Zhang, Ke Liu, Zhongshan Liu, Zhaolong Wang, Chunxia Hua, Taihong Liu*, and Yu Fang*. High-Performance Ketone Sensing in Vapor Phase Enabled by o-Carborane-Modified Cyclometalated Alkynyl-Gold(III) Complex-Based Fluorescent Films. ACS Appl. Mater. Interfaces 2021, 13(4), 5625-5633. Doi: 10.1021/acsami.0c21424.（共同通讯作者）

2020年

[14] Rong Miao, Jing Li, Zhenshan Luo, Haiqi Yu, Taihong Liu*, and Yu Fang*. Photochemical Synthesis of Solvatochromic Fluorophore from the C–C Coupling Reaction for Undergraduate Laboratory Experiment. J. Chem. Edu.  2020, 97(12), 4469-4474 .（共同通讯作者）

[13] Quan Liu, Taihong Liu*, and Yu Fang*. Perylene Bisimide Derivatives-based Fluorescent Film Sensors: From Sensory Materials to Device Fabrication. Langmuir 2020, 36(9), 2155-2169.（共同通讯作者）

[12] Taihong Liu*, Lvjie Yang, Wan Feng, Ke Liu, Qian Ran, Weina Wang, Quan Liu, Haonan Peng, Liping Ding, and Yu Fang*. Dual-Mode Photonic Sensor Array for Detecting and Discriminating Hydrazine and Aliphatic Amines. ACS Appl. Mater. Interfaces 2020, 12(9), 11084-11093. Doi: 10.1021/acsami.0c00568.

[11] Taihong Liu, Rong Miao, Haonan Peng, Jing Liu, Liping Ding, and Yu Fang*. Adlayer Chemistry on Film-Based Fluorescent Gas Sensors. Acta Phys. -Chim. Sin. 2020, 36(10), 190825. [刘太宏, 苗荣, 彭浩南, 刘静, 丁立平, 房喻*. 薄膜基荧光气体传感器中的涂层化学. 物理化学学报 2020, 36(10), 190825.]

2019年

[10] Ke Liu, Jing Zhang, Ling Xu, Jing Liu, Liping Ding, Taihong Liu* and Yu Fang*. Film-Based Fluorescent Sensing: A "Chemical Nose" for Nicotine. Chem. Commun. 2019, 55: 12679-12682. Doi: 10.1039/C9CC06771J.（共同通讯作者）

[9] Quan Liu, Somnath Mukherjee, Rongrong Huang, Ke Liu, Taihong Liu,* Kaiqiang Liu, Rong Miao, Haonan Peng and Yu Fang*. Naphthyl End-capped Terthiophene-based Chemiresistive Sensors for Biogenic Amine Detection and Meat Spoilage Monitoring. Chem.-Asian J. 2019, 14(15): 2751-2758.（共同通讯作者）

[8] Taihong Liu, Lvjie Yang, Jing Zhang, Ke Liu, Liping Ding, Haonan Peng, Kevin D. Belfield* and Yu Fang*. Squaraine-hydrazine Adducts for Fast and Colorimetric Detection of Aldehydes in Aqueous Media. Sens. Actuators B 2019, 292, 88-93.

[7] Ke Liu, Zhaolong Wang, Congdi Shang, Xiao Li, Haonan Peng, Rong Miao, Liping Ding, Jing Liu, Taihong Liu* and Yu Fang*. Unambiguous Discrimination and Detection of Controlled Chemical Vapors by a Film‐Based Fluorescent Sensor Array. Adv. Mater. Technol. 2019, 4(7): 1800644. DOI: 10.1002/admt.201800644.（共同通讯作者）

2018年

[6] Taihong Liu^#, Xinglei Liu^#, Yuanwei Zhang, Mykhailo V. Bondar, Yu Fang, and Kevin D. Belfield*. Far-red to NIR-emitting Adamantyl-functionalized Squaraine Dye: J-Aggregation, Dissociation and Cell Imaging. Eur. J. Org. Chem. 2018, 2018 (30): 4095-4102.

[5] Jinling Zhang, Ke Liu, Gang Wang, Congdi Shang, Haonan Peng, Taihong Liu* and Yu Fang*. Detection of Gaseous Amines With A Fluorescent Film Based on A Perylene Bisimide-functionalized Copolymer. New J. Chem. 2018, 42: 12737-12744. DOI: 10.1039/C8NJ02540A.（共同通讯作者）

[4] 刘太宏, 房喻*.  薄膜基荧光气体传感器. 应用化学 2018, 35 (9): 1133-1137. (荣获“2018年度《应用化学》优秀论文奖”)

[3] Taihong Liu*, Ke Liu, Jinling Zhang, Zhaolong Wang. Terpyridine Functionalized Oligothiophene: Cadmium(II) Ion Sensing via Visualization and Fluorescence. ChemistrySelect 2018, 3 (20): 5559-5565. DOI: 10.1002/slct.201800841.

[2] Ke Liu, Congdi Shang, Zhaolong Wang, Yanyu Qi, Rong Miao, Kaiqiang Liu, Taihong Liu, and Yu Fang*. Non-contact Identification and Differentiation of Illicit Drugs Using Fluorescent Films. Nat. Commun. 2018, 9, 1695(1-11). DOI: 10.1038/s41467-018-04119-6.

[1] Taihong Liu, Xinglei Liu, Weina Wang, Zhipu Luo, Muqiong Liu, Shengli Zou, Cristina Sissa, Anna Painelli, Yuanwei Zhang, Mikas Vengris, Mykhailo V. Bondar, David J. Hagan, Eric W. Van Stryland, Yu Fang, and Kevin D. Belfield*. Systematic Molecular Engineering of a Series of Aniline-Based Squaraine Dyes and Their Structure-Related Properties. J. Phys. Chem. C 2018, 122 (7): 3994-4008. DOI: 10.1021/acs.jpcc.7b11997.

【荣誉奖励】

 [3] 陕西高校青年创新团队（2019年度，5/12）

 [2] 陕西省科学技术一等奖（分子凝胶基材料的创新制备与应用，2018年度，7/11）

 [1] 陕西高等学校科学技术一等奖（分子凝胶基材料的创新制备与应用，2018年度，7/11）

【教学经历】

[5] 2020年教学模式创新与实践研究专项基金，2020年4月-2021年4月，主持，已结题.

[4] 电导法测定表面活性剂临界胶束浓度实验教学的思考 《科学咨询》，2020年第19期，P15-16.

[3] 2021年、2020年、2019年大学生创新创业训练计划项目指导

[2] 物理化学实验

[1] 物理化学教学

【发明专利】

[4] 专利名称：一类寡聚噻吩功能化邻位碳硼烷衍生物及其合成方法和光限幅特性应用 ，申请号：202110325354.3，申请时间：2021年03月26日

[3] 专利名称：一类具有双光子吸收特性的轴向配位复合物材料 ，申请号：2020109763600，申请时间：2020年09月16日

[2] 专利名称：一种双模式传感器阵列及其区分识别肼和有机胺的应用（申请号：2020100704950），申请时间：2020年01月21日

[1] 专利名称：一种水溶性方酸菁衍生物及其合成方法和检测醛类化合物的应用，专利号：2019102270027，授予时间：2021年10月19日

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部分研究论文（2017年10月前）：

(1) T. Liu, X. Liu, M. Valencia, B. Sui, Y. Zhang, and K. D. Belfield*.Novel far-red emitting TEG-substituted squaraine dye: synthesis, optical properties, and selective detection of cyanide in aqueous solution. Eur. J. Org. Chem. 2017, 3957-3964.

(2) T. Liu, M. V. Bondar, K. D. Belfield^*, D. Anderson, A. E. Masunov, D. J. Hagan, and E. W. V. Stryland^*. Linear photophysics and femtosecond nonlinear spectroscopy of a star-shaped squaraine derivative with efficient two-photon absorption. J. Phys. Chem. C 2016, 120, 11099-11110.

(3) B. Sui, S. Tang, T. Liu, B. Kim, K. D. Belfield^*. Novel BODIPY-based fluorescence turn-on sensor for Fe³⁺ and its bioimaging application in living cells. ACS Appl. Mater. Interfaces 2014, 6 (21), 18408-18412.

(4) K. Liu, T. Liu, X. Chen, X. Sun, Y. Fang^*. Fluorescent films based on molecular-gel networks and their sensing performances. ACS Appl. Mater. Interfaces2013, 5, 9830-9836.

(5) K. Zhao, T. Liu, G. Wang, X. Chang, D. Xue, K. D. Belfield, Y. Fang^*. A butterfly-shaped pyrene derivative of cholesterol and its uses as a fluorescent probe. J. Phys Chem. B 2013, 117, 5659-5667.

(6) T. Liu, K. Zhao, L. Ding, S. Yin and Y. Fang^*. Synthesis, optical properties and explosives sensing performances of a series of novel π-conjugated aromatic end-capped oligothiophenes. J. Hazard. Mater. 2013, 246-247, 52-60.

(7) T. Liu, L. Ding, K. Zhao, W. Wang and Y. Fang^*. Single-layer assembly of pyrene end-capped terthiophene and its sensing performances to nitroaromatic explosives. J. Mater. Chem. 2012, 22, 1069-1077.

(8) Y. Xin^*, Q. Wang, T. Liu, L. Wang, J. Li, Y. Fang^*. A portable and autonomous multichannel fluorescence detector for on-line and in situ explosive detection in aqueous phase. Lab on a chip, 2012, 12 (22), 4821-4828.

(9) H. Xia^*, T. Liu, L. Gao, L. Yan, J. Wu. Development of film sensors based on ZnO nanoparticles for amine gas detection. Appl. Surf. Sci. 2011, 258 (1), 254-259.

(10) T. Liu, L. Ding^*, G. He, Y. Yang, W. Wang and Y. Fang^*. Photochemical stabilization of terthiophene and its utilization as a new sensing element in the fabrication of monolayer-chemistry-based fluorescent sensing films. ACS Appl. Mater. Interfaces 2011, 3, 1245-1253.

(11) T. Liu, Y. Nie, G. He, Y. Zhang, L. Ding, Y. Fang^*. Quaterthiophene-based fluorescent films: preparation and sensing performance to formaldehyde vapor. Chem. J. Chinese U. 2010, 31, 524-529.

(12) T. Liu, G. He, M. Yang and Y. Fang^*. Monomolecular-layer assembly of oligothiophene on glass wafer surface and its fluorescence sensitization by formaldehyde vapor. J. Photochem. Photobiol. A: Chem. 2009, 202, 178-184.